Passive Q-Switching is preferred for simplicity of manufacturing and operation, low cost, and reduced system size and weight. Cr4+: YAG (Y3Al5O12) crystals are excellent for passive Q-Switching diode pumped or lamp-pumped Nd: YAG, Nd: YLF, Yb: YAG or other Nd and Yb doped lasers  at wavelengths from 1.0 to 1.2mm. Because they are chemically stable, durable, UV resistant, have good thermal conductivity, have a high  damage threshold (>500mW/cm2) and ease of operation, they will replace traditional materials such as LiF, organic dye and color centers.

Basic Properties of Cr4+:YAG

Formula Cr4: Y3AI5O12
Crystal Structure Cubic Garnet
Dopant Level 0.03 mol% - 0.05 mol%
Hardness 8.5 (Mohs)
Damage Threshold >500MW/cm2
Refractive Index 1.82 @1064nm

Capability

ATTRIBUTE COMMERCIAL HIGH PRECISION
Flatness λ/4 λ/10
Wavefront Distortion λ/4 λ/10
Surface Quality 20-10 scratch and dig 10-5 scratch and dig

AR coatings and HR coatings are also available. The initial transmission (To) can be controlled from 10% to 95% according to customer  requirements. Standard size Cr4+:YAG crystals of 3x3mm2 with To=80% or 90% are in stock and available for immediate delivery.

Preliminary experiments done on Casix\'s Cr:YAG crystals show that the pulse width of passively Q-switched lasers can be as short as 9ns for  diode pumped Nd:YAG lasers with repetition as high as 10kHz for diode pumped Nd:YVO4 lasers. Furthermore, an efficient green output @532nm and UV output@355nm and 266nm were generated after a subsequent intra-cavity SHG in KTP for diode pumped and passive Q-switched Nd:YAG and Nd:YVO4 lasers.

Cr:YAG is also a laser crystal with tunable output from 1.35um to 1.6um. It can generate ultrashort pulse lasers (to fs pulsed) when pumped  by Nd:YAG lasers at 1.064um.