Potassium Titanyle Arsenate(KTiOAsO4), or KTA crystal, is an excellent nonlinear optical crystal for Optical Parametric Oscillation (OPO) application. It has better non-linear optical and electro-optical coefficients, significantly reduced absorption in the 2.0-5.0 µm region, broad angular and temperature bandwidth, low dielectric constants. And its low ionic conductivities   result in higher damage threshold compared with KTP .


Crystal Structure

Orthorhombic, point group mm2,

Lattice parameter

a=13.125À, b=6.5716À, c=10.786À

Melting point

1130℃

Mohs Hardness

near 5

Density

3.454g/cm3

Thermal conductivity

K1:1.8W/m/K;  K2: 1.9W/m/K;  K3: 2.1W/m/K

Table 2.Optical and Nonlinear Optical Properties


TransparencyRange

350-5300nm

Absorption Coefficients

@ 1064 nm <0.05 %/cm 
@ 1533 nm <0.05 %/cm 
@ 3475 nm <5%/cm

NLO susceptibilities(pm/V)

d31 = 2.76, d32 = 4.74, d33 = 18.5 , d15 = 2.3, d15 = 3.2

 

Sellmeier Equation

Ni2=Ai+Biλ2/(λ2-Ci2)-Diλ2(λin um)

index A B C D Nx 1.90713 1.23522 0.19692 0.01025 Ny 2.15912 1.00099 0.21844 0.01096 Nz 2.14768 1.29559 0.22719 0.01436

 

Electro-optical constants(pm/V)

(low frequency)

γ33=37.5;γ23=15.4;γ13=11.5

SHG Phase Matchable Range

1083-3789nm